Production and investigating the physical, mechanical and anti-microbial characteristics of LDPE nano-composite packaging films incorporating Ag, ZnO and Cuo nanoparticles

Document Type : Research Paper

Authors

1 Associate Prof., Department of Food Science, College of Agriculture, University of Tabriz

2 Department of Food Science, College of Agriculture, University of Tabriz, Tabriz, IRAN

3 Department of Chemical & Petroleum Engineering, University of Tabriz, Tabriz, IRAN

Abstract

The main objective of this study was to produce LDPE active films containing metallic nanoparticles (Ag, ZnO and CuO) and to investigate their physical, mechanical and anti-microbial characteristics. Three types of metallic nanoparticles at concentrations of 1% (w/w) were added to low density polyethylene (LDPE) and the films were prepared using melt extrusion technique. SEM results indicated rather uniform distribution of nanoparticles in polymeric matrix. Ag containing film showed highest tensile strength and Cu containing film showed the highest elongation to break values. Films containing ZnO nanoparticles had the highest UV absorption. A 99.9% reduction in Escherichia coli and a 90% reduction in Staphylococcus aureus were observed for films containing all nanoparticles which were evaluated by colony counting. However, ZnO nanoparticles were more effective in retarding the growth of S. areus and Ag and Cuo were more effective for E. coli.

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Main Subjects


  1. Ahvenainen, R. (2003) Novel food packaging techniques. Woodhead Pub. Inc., England.

 

  1. Brody, A.L., Strupinsky, E.R. & Kline, L.R. (2001) Active packaging for food applications. Florida: CRC Press LLC, Boca Raton

 

  1. Bajpai, S.K., Chand, N. & Chaurasia, V. (2009) Investigation of water vapor permeability and antimicrobial property of Zinc oxide nanoparticles loaded chitosan-based edible film. Applied polymer science, 115(2), 674-683.

 

  1. Bruna, J.E., Peñaloza, A., Guarda, A., Rodríguez, F. & Galotto, M.J. (2012) Development of MtCu2+/LDPE nanocomposites with antimicrobial activity forpotential use in food packaging. Applied Clay Science, 58, 79-87.

 

  1. Chae, D.W. & Kim, B.C. (2005) Characterization on polystyrene/zinc oxide nanocomposites prepared from solution mixing. Poymer for Advanced  Technologies, 16(11-12), 846–850.

 

  1. Emamifar, A., Kadivar, M., Shahedi, M. & Soleimanian-Zad, S. (2011) Effect of nanocomposite packaging containing Ag and ZnO on inactivation of Lactobacillus plantarum in orange juice. Food Control, 22(3-4), 408-413.

 

  1. Emamifar, A., Kadivar, M., Shahedi, M. & Soleimanian-Zad, S. (2010) Evaluation of nanocomposite packaging containing Ag and ZnO on shelf life of freshorange juice. Innovative Food Science and Emerging Technologies, 11(4), 742–748.

 

  1. Hong, S. & Rhim, J. W. (2012) Preparation and properties of melt-intercalated linear low density polyethylene/clay nanocomposite films prepared by blow extrusion. LWT-Food Science and Technology, 48(1), 43-51.

 

  1. Jokar, M., Abdul Rahman, R., Ibrahim, N.A., Abdullah, L.C. & Ping Tan C. (2010) Melt production and antimicrobial efficiency of low-density polyethylene (LDPE)-silver nanocomposite film. Food Bioprocess Technolgy, 5(2), 719–728.

 

  1. Li, L.H., Deng, J.C., Deng, H.R., Liu, Z.L. & Li, X.L. (2010) Preparation, characterization and antimicrobial activities of chitosan/Ag/ZnO blend films. Chemical Engineering 160(1), 378–382.

 

  1. Li, S.C. & Li, Y.N. (2010) Mechanical and antimicrobial proprties of modified nano-ZnO/high density polyethylene composite films with low doped content of nano-ZnO. Applied Polymer Science, 116(5), 2965-2969.

 

  1. Li, X., Xing, Y., Jiang, Y., Ding, Y. & Li, W. (2009) Antimicrobial activities of ZnO powder-coated PVC film toinactivate food pathogens. Food Science and Technology, 44(11), 2161–2168.

 

  1. Li, X., Li, W., Jiang, Y., Ding, Y., Yun, J., Tang, Y. & Zhang, P. (2011) Effect of nano-ZnO-coated active packaging on quality of fresh-cut‘Fuji’ apple. Food Science and Technology, 46(9), 1947–1955.

 

  1. Liorens, A., Lloret, E., Picouet, P.A., Trbojevich, R. & Fernandez, A. (2012) Metallic-based microand nanocompositesin food contactmaterials and activefood packaging. Trends in Food Science & Technology, 24(1), 19-29.

 

  1. Liu, Y.,  He, L., Mustapha, A., Li, H., Hu, Z.Q. & Lin, M. (2009) Antibacterial activities of zinc oxide nanoparticles against Escherichia coli O157:H7. Applied Microbiology, 107(4), 1193–1201.

 

  1. Rhim, J.W., Wang, L.F. & Hong, S.I. (2013) Preparation and characterization of agar/silver nanoparticles composite films with antimicrobial activity. Food Hydrocolloids, 33(16)327-335

 

  1. Rooney, M.L. (1995) Active food packaging. Australia: Blackie Academic & Professional

 

 

  1. Seo, J., Jeon, G., Sung Jang, E., Khan, S.B. & Han, H. (2011) Preparation and properties of poly(propylene carbonate) and nanosized ZnO composite films for packaging applications. Applied Polymer Science, 122(2), 1101-1108.

 

  1. Shankar, S., Teng, X., Li, G. & Rhim, J.W. (2014) Preparation, characterization, and antimicrobial activity of gelatin/ZnO nanocomposite Films. Food Hydrocolloids, DOI: 10.1016/j.foodhyd.2014.12.001

 

  1. Tewari, G. & Juneja, V.K.(2007) Advances in Thermal and Non-Thermal Food Preservation: Blackwell Publishing

 

  1. Wang, Y., Zhang, Q., Zhang, C. & Li, P. (2012) Characterisation and cooperative antimicrobial properties of chitosan/nano-ZnOcomposite nanofibrous membranes. Food Chemistry, 132(1), 419-427.

 

  1. Zapata, P.A., Tamayo, L., Páez, M., Cerda, E., Azócar, I. & Rabagliatil, F.B. (2011) Nanocomposites based on polyethylene and nanosilver particlesproduced by metallocenic ‘‘in situ’’ polymerization: synthesis,characterization, and antimicrobial behavior. European Polymer Journal, 47(8), 1541–1549.

 

Zhou, L., Lv, S., He, G., He, Q. &  Shi, B. (2011) Effect of PE/AG2O nano-packaging on the quality of apple sclices. Journal of Food Quality, 34(3), 171-176.